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Warning: This experiment uses highly corrosive chemicals and produces toxic gases.
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This should be performed with gloves in a fume hood.
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Greetings fellow nerds.
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In a previous video we examined the chemical resistance of gold.
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In this video we're going examine the chemical resistance of platinum.
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Here I have a one troy ounce bar of platinum metal.
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The first test will be in hydrochloric acid so I'm wrapping it in aluminum foil for comparison purposes.
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Here is the concentrated hydrochloric acid.
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I'm putting this round bottom flask over it to keep it from splashing out.
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What's happening is the acid is reacting with the aluminum foil to form hydrogen gas and aluminum trichloride.
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Since it's highly concentrated the aluminum trichloride hydrate is precipitating out as a powder.
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I'm going to add some water to completely dissolve it.
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And here is the platinum bar. Let me get it out of there.
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The hydrochloric acid completely destroyed the aluminum but the platinum bar is perfectly fine.
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Now for the sulfuric acid test.
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I have here some sugar and I'm adding to it some concentrated sulfuric acid.
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Let me toss in the platinum bar.
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And now we wait.
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What's happening is the sulfuric acid is removing water from the sugar and leaving behind carbon.
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Now the platinum bar is embedded in this pillar of carbon so let me retrieve it.
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And there it is.
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Oh I think I scratched it when I jabbed it with my spatula. Oh well.
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The sulfuric acid itself did no damage to the platinum.
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Now for the nitric acid test.
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For comparison I'm also going to toss in a piece of copper.
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The nitric acid is reacting with the copper to produce copper nitrate and this brown nitrogen dioxide gas.
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Okay looks like the reaction is done.
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And here is platinum bar, completely immune to the nitric acid.
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Now for the reaction with molten sodium hydroxide.
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I'm putting these pellets on the surface and now I'm going to heat it with a torch.
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The sodium hydroxide is melting and as I continue heating it... oh look, it's turning brown.
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Either the sodium hydroxide is turning brown or the platinum is.
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Let me let it cool and we'll remove the sodium hydroxide to be certain.
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The sodium hydroxide is solidifying so we'll need to dissolve it in water.
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Here we go.
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Looks like the brown color is permanent.
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Platinum can be tarnished by molten sodium hydroxide.
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What happened was under molten alkali conditions platinum is oxidized by air.
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So what we have here is a surface coating of platinum oxide.
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Anyway there we have it, platinum can be damaged by molten sodium hydroxide.
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For those interested, of course I'll be dissolving this in aqua regia in a later video.
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Thanks for watching.
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In this video we'll look at the chemical resistance of gold.
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In this video we're going to dissolve platinum in a combination of nitric and hydrochloric acids, better known as aqua regia.