Butthisis a reasonableassumptionbecause, generallyspeaking, itmightbe a very, veryinfinitepresentlysmallfractionofthetotalvolumeofthespacethatthey'rebouncingaroundit.
Well, what I imagineisif I have a balloonlikethisand I havesomegasintheballoonif I trytodecreasethevolumebymakingit a smallerballoonwithoutlettingoutanyotherairorwithoutchangingthetemperature.
So I'm notchanging t and n what's goingtohappentothepressure?
If I weretomakethecontainerbigger, notchangingonceagainthetemperatureorthenumberofmoles I haveinsideofthecontainer, it's goingtolowerthepressuresoitlookslikevolumeandpressuremoveinverselywitheachother.
Well, if I startwithmyballoonexampleandyoucouldrunthisexampleififyoudon't believeme, ifyoutake a balloonandyouweretoblowitupatroomtemperatureandthenifyouweretoputitintothefridge, youshouldseewhathappens.
It's goingtoshrink.
Andyoumightsay, Whyisitshrinking?
Well, youcouldimaginethattheparticlesinsidetheblueare a littlelessvigorousatthatpoint.
Theyhavelowerindividualkineticenergies, andso, inorderforthemtoexertthesamepressuretooffsetatmosphericpressureontheoutside, you'regoingtohave a lowervolume.