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  • This episode is sponsored by Coursera:

  • one hundred percent online learning from the world's best universities and companies.

  • [♪ INTRO]

  • Exploring space has arguably been one of humanity's greatest achievements.

  • We've landed people on the Moon, put hardware on and around other planets,

  • and launched all kinds of powerful space telescopes and satellites.

  • That work has helped us learn more about the history of the universe and our place in it,

  • but it also comes at a cost: In striving to learn about other worlds, we've actually

  • been damaging our own.

  • Today, building and launching rockets often involves using toxic cleaning solvents

  • and dumping tons of greenhouse gases into the atmosphere.

  • And while reusable rockets and boosters are a great step,

  • we're going to have to do a lot more if we really want to make the space industry Earth-friendly.

  • That's where these four technologies can help us out.

  • The environmental engineering part of space exploration

  • isn't something that's talked about a whole lot, but the science is really fascinating.

  • Engineers are approaching it from a bunch of angles,

  • but for now, we're going to focus on two main research areas.

  • First, scientists are investigating propellants, including a type called hypergolic propellants,

  • which are used in things like rockets and satellites.

  • Unlike other propellants, these ignite spontaneously

  • when their fuel and oxidizer come together, without the need of something like a spark.

  • Most commonly, they're made with some variety of hydrazine.

  • Hydrazine has been used in everything from the Space Shuttles to Mars missions,

  • so it's great for exploration, but it's also incredibly toxic and corrosive.

  • So it's no surprise that researchers are looking for alternatives.

  • And the good news is that they've found some!

  • One possible alternative to hydrazine-bearing propellants

  • is a salt called ammonium dinitramide, or ADN for short.

  • When it's heated, ADN breaks down into just nitrogen, oxygen, and water,

  • so it's pretty environmentally clean.

  • It's also significantly less dangerous to handle and work with.

  • The problem is, ADN is normally a solid and isn't very reactive.

  • It can be dissolved in things like methanol or ammonia,

  • but even then, it can take temperatures of more than 1600 degrees Celsius to ignite it.

  • So recently, scientists have been looking into ways to make ADN ignition more spontaneous.

  • And in 2018, a team in Germany published some exciting new results.

  • Their trick was to make a really good catalyst.

  • Catalysts help increase the surface area available for a reaction to take place,

  • and they reduce the amount of heat needed to get things started.

  • Traditionally, catalysts have been a bunch of tiny pellets

  • that the propellant has to move through, and that's worked pretty well.

  • Using something like this, you can get ADN to ignite at around 350 degrees Celsius.

  • But that still means you have to preheat the mixture before you can use it,

  • which takes energy and, maybe more importantly, it takes time.

  • And if you need to move your spacecraft in an emergency, time just isn't something you have.

  • So, this team wanted to see if they could reduce ADN's ignition temperature

  • even more by using a better catalyst.

  • And to do it, they turned to 3D printing.

  • In this new study, they modeled and 3D printed a honeycomb structure called a monolith.

  • It's basically a ceramic framework covered in a metal catalyst.

  • Compared to the pellets, this complex structure has an incredibly high surface area,

  • which massively increases the speed and efficiency of the reaction.

  • Using monoliths, the scientists were able to reduce the ignition temperature of ADN

  • from 350 degrees to just 100 degrees Celsius.

  • Which is amazing progress!

  • Their next challenge is to get the reaction started at room temperature.

  • Because of the chemistry involved, that will probably take more than just a fancy catalyst,

  • but cold-starting green propellants are finally on the horizon.

  • Now, ADN isn't the only green solution out there.

  • Scientists are also researching another new kind of propellant, called a metal-organic framework.

  • These are the solid structures made of groups of metal ions and an organic molecule called a linker.

  • They're normally stable, and they've traditionally been used as catalysts

  • to help with gas separation and storage in various industries.

  • But now, scientists are trying to figure out if these frameworks could do more.

  • They're investigating if they could release huge amounts of energy in the same way that hydrazine does.

  • And they've found that they can, with some adjustments.

  • By adding simple chemicals like vinyl or acetylene to the metal-organic framework,

  • researchers have found that the stable, solid structure can become incredibly reactive.

  • On contact with an oxidizer like nitric acid, it ultimately breaks down

  • and releases vast amounts of heat.

  • And some fire, for good measure.

  • In April 2019, scientists at McGill University in Canada reported that they had used this system

  • to get their metal-organic frameworks to ignite at room temperature.

  • Some of them even ignited just two milliseconds after contact with an oxidizer.

  • Which, like, is pretty close toinstantaneous”.

  • So far, though, these compounds have only been tested in the lab,

  • and plenty more research is needed before they can be incorporated into any rocket thrusters.

  • But if they can be, they would be a huge step forward in the green propellant world.

  • Then againit's not just the rockets that can damage the environment.

  • Space hardware can also have a negative impact on Earth even before it gets into space.

  • That's because spacecraft components have to be ultra-clean.

  • A speck of dust, or even the oil from a fingerprint, could be enough to damage

  • or interfere with the sensitive instruments on-board space-bound machinery.

  • You also have to make sure a bunch of bacteria doesn't hitch a ride;

  • otherwise, you could contaminate whatever world you're going to study.

  • So all that to say, cleaning spacecraft is a really important job.

  • To remove any possible contaminants, spacecraft components have been cleaned

  • with everything from the highly toxic trichloroethylene to various alcohols.

  • These solvents are often aggressive.

  • They have to be, to get rid of the most stubborn substances.

  • But they can also be dangerous for humans and the environment.

  • So, like with propellants, scientists are looking into alternatives.

  • One possibility is supercritical carbon dioxide.

  • Solid and liquid carbon dioxide are already used for cleaning,

  • but you can unlock more of CO2's powers by making it supercritical.

  • By keeping it above 31 degrees Celsius, and at pressures of more than 7.3 megapascals,

  • CO2 becomes a supercritical fluid with properties of both a liquid and a gas.

  • More specifically, it flows and fills its container like a gas, but has a density like a liquid.

  • That means it can penetrate into porous solids, and dissolve small, lightweight molecules.

  • Back in 2014, NASA research showed that it can be used to remove sticky greases

  • and clean small, delicate spacecraft parts with about 90% effectiveness.

  • For comparison, a simple rinse with the most common solvents

  • managed to shift just 77% of the grease.

  • As kind of a cool bonus, this carbon dioxide could be pulled

  • straight from the atmosphere, which would mean no net greenhouse gases.

  • And finally, we have one more cleaning option for you, and it might seem a bit more futuristic: plasma.

  • When a gas like oxygen or hydrogen is exposed to a strong electric field,

  • the electrons are ripped from the gas' atoms,

  • and that creates a high-energy mix of ions and electrons: a plasma.

  • These particles have enough energy to attack any contaminants on a surface,

  • like by knocking them off or by breaking them down into smaller pieces.

  • So by sticking something in a chamber and blasting plasma at it,

  • even oddly-shaped surfaces can be made squeaky clean.

  • Admittedly, the plasma can attack the outermost layers of whatever it is you're cleaning,

  • but it's not enough to be actually noteworthy.

  • Like with supercritical carbon dioxide, plasma cleaning is also pretty eco-friendly,

  • since when you're done and the electric field is turned off,

  • you're left with just the neutral gas you started with.

  • Both of these cleaning methods have already been embraced by NASA

  • at places like Kennedy Space Center.

  • But while the science is pretty well understood,

  • the need for special equipment and controlled conditions means it's still pretty costly.

  • At the moment, these green solutions to cleaning and propulsion aren't fully developed,

  • or economically appealing, but they're a really promising step in the right direction.

  • And as we keep learning, new innovations like these

  • could really help shape the future of green space exploration.

  • Talking about subjects like this is a good reminder that there's no one, standard job

  • in the space industry.

  • It takes all kinds of skills to help us explore the universe.

  • And if you want to brush up on some of your skills, you can check out a course at Coursera.

  • Coursera was founded in 2012 by two computer science professors from Stanford University.

  • They wanted to share their knowledge with the world,

  • so they put their courses online for anyone to check out.

  • Today, they have over 3,000 courses covering everything

  • from astronomy to artificial intelligence to data science.

  • So whether you're looking to make a career change

  • or just grow in a skill you already have, there's something there for you.

  • They even have a course about science writing and communication.

  • Which, y'know, we're big fans of around here.

  • Right now, more than 35 million people around the world are learning on Coursera.

  • And if you want to check them out for yourself,

  • you can click the link in the description to learn more.

  • [♪ OUTRO]

This episode is sponsored by Coursera:

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