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  • The one thing that probably causes some of the most pain

  • in chemistry, and in organic chemistry, in particular, is

  • just the notation and the nomenclature or the naming

  • that we use.

  • And what I want to do here in this video and really the next

  • few videos is to just make sure we have a firm grounding

  • in the notation and in the nomenclature or how we name

  • things, and then everything else will

  • hopefully not be too difficult.

  • So just to start off, and this is really a little bit of

  • review of regular chemistry, if I just have a chain of

  • carbons, and organic chemistry is dealing

  • with chains of carbons.

  • Let me just draw a one-carbon chain, so it's really kind of

  • ridiculous to call it a chain, but if we have one carbon over

  • here and it has four valence electrons, it

  • wants to get to eight.

  • That's the magic number we learned in

  • just regular chemistry.

  • For all molecules, that's the stable valence structure, I

  • guess you could say it.

  • A good partner to bond with is hydrogen.

  • So it has four valence electrons and then hydrogen

  • has one valence electron, so they can each share an

  • electron with each other and then they

  • both look pretty happy.

  • I said eight's the magic number for everybody except

  • for hydrogen and helium.

  • Both of them are happy because they're only trying to fill

  • their 1s orbital, so the magic number for

  • those two guys is two.

  • So all of the hydrogens now feel like

  • they have two electrons.

  • The carbon feels like it has eight.

  • Now, there's several ways to write this.

  • You could write it just like this and you can see the

  • electrons explicitly, or you can draw little lines here.

  • So I could also write this exact molecule, which is

  • methane, and we'll talk a little bit more about why it's

  • called methane later in this video.

  • I can write this exact structure like this: a carbon

  • bonded to four hydrogens.

  • And the way that I've written these bonds right here you

  • could imagine that each of these bonds consists of two

  • electrons, one from the carbon and one from the hydrogen.

  • Now let's explore slightly larger chains.

  • So let's say I have a two-carbon chain.

  • Well, let me do a three-carbon chain so it really

  • looks like a chain.

  • So if I were to draw everything explicitly it might

  • look like this.

  • So I have a carbon.

  • It has one, two, three, four electrons.

  • Maybe I have another carbon here that has-- let me do the

  • carbons in slightly different shades of yellow.

  • I have another carbon here that has one,

  • two, three, four electrons.

  • And then let me do the other carbon in that first yellow.

  • And then I have another carbon so we're going to have a

  • three-carbon chain.

  • It has one, two, three, four valence electrons.

  • Now, these other guys are unpaired, and if you don't

  • specify it, it's normally going to be hydrogen, so let

  • me draw some hydrogens over here.

  • So you're going to have a hydrogen there, a hydrogen

  • over there, a hydrogen over here, a hydrogen over here, a

  • hydrogen over there, a hydrogen over here, almost

  • done, a hydrogen there, and then a hydrogen there.

  • Now notice, in this molecular structure that I've drawn, I

  • have three carbons.

  • They were each able to form four bonds.

  • This guy has bonds with three hydrogens and another carbon.

  • This guy has a bond with two hydrogens and two carbons.

  • This guy has a bond with three hydrogens and then this carbon

  • right here.

  • And so this is a completely valid molecular structure, but

  • it was kind of a pain to draw all of these

  • valence electrons here.

  • So what we typically would want to do is, at least in

  • this structure, and we're going to see later in this

  • video there's even simpler ways to write it, so if we

  • want at least do it with these lines, we can

  • draw it like this.

  • So you have a carbon, carbon, carbon, and then they are

  • bonded to the hydrogens.

  • So you'll almost never see it written like this because this

  • is just kind of crazy.

  • Hyrdrogen, hydrogen-- at least crazy to write.

  • It takes forever.

  • And it might be messy, like it might not be clear where these

  • electrons belong.

  • I didn't write it as clearly as I could.

  • So they have two electrons there.

  • They share with these two guys.

  • Hopefully, that was reasonably clear.

  • But if we were to draw it with the lines, it

  • looks just like that.

  • So it's a little bit neater, faster to draw, same exact

  • idea here and here.

  • And in general, and we'll go in more detail on it, this

  • three-carbon chain, where everything is a single bond,

  • is propane.

  • Let me write these words down because it's helpful to get.

  • This is methane.

  • And you're going to see the rhyme-- you're going to see

  • the reason to this naming soon enough.

  • This is methane; this is propane.

  • And there's an even simpler way to write propane.

  • You could write it like this.

  • Instead of explicitly drawing these bonds, you could say

  • that this part right here, you could write that that part

  • right there, that is CH3, so you have a CH3, connected to

  • a-- this is a CH2, that is CH2 which is then connected to

  • another CH3.

  • And the important thing is, no matter what the notation, as

  • long as you can figure out the exact molecular structure, as

  • long as you can-- so there's this last CH3.

  • Whether you have this, this, or this, you know what the

  • molecular structure is.

  • You could draw any one of these given any of the others.

  • Now, there's an even simpler way to write this.

  • You could write it just like this.

  • Let me do it in a different color.

  • You literally could write it so we have three carbons.

  • So one, two, three.

  • Now, this seems ridiculously simple and you're like, how

  • can this thing right here give you the same information as

  • all of these more complicated ways to draw it?

  • Well, in chemistry, and in organic chemistry in

  • particular, any of these-- let me call it a line diagram or a

  • line angle diagram.

  • It's the simplest way and it's actually probably the most

  • useful way to show chains of carbons or to

  • show organic molecules.

  • Once they start to get really, really complicated, because

  • then it's a pain to draw all of the H's, but when you see

  • something like this, you assume that the end points of

  • any lines have a carbon on it.

  • So if you see something like that, you assume that there's

  • a carbon at that end point, a carbon at that end point, and

  • a carbon at that end point.

  • And then you know that carbon makes four bonds.

  • There are no charges here.

  • All the carbons are going to make four bonds, and each of

  • the carbons here, this carbon has two bonds, so the other

  • two bonds are implicitly going to be with hydrogens.

  • If they don't draw them, you assume that they're going to

  • be with hydrogens.

  • This guy has one bond, so the other three

  • must be with hydrogen.

  • This guy has one bond, so the other three must be hydrogens.

  • So just drawing that little line angle thing right there,

  • I actually did convey the exact same information as this

  • depiction, this depiction, or this depiction.

  • So you're going to see a lot of this.

  • This really simplifies things.

  • And sometimes you see things that are in between.

  • You might see someone draw it like this, where they'll write

  • CH3, and then they'll draw it like that.

  • So that's kind of combining this way of writing the

  • molecule where you write the CH3's for the end points, but

  • then you implicitly have the CH2 on the inside.

  • You assume that this end point right here is a C and it's

  • bonded to two hydrogens.

  • So these are all completely valid ways of drawing the

  • molecular structures of these carbon chains or of these

  • organic compounds.

The one thing that probably causes some of the most pain

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