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  • Sometimes Brady and Neil do experiments that are just for fun

  • And then they ask me what's going on.

  • So the experiment they decided to do was to

  • drop a piece of burning iron wool

  • this is finely divided iron wire

  • that looks a bit like my hair.

  • Slightly darker.

  • And you can light such iron wool

  • by putting it across the terminals of a small battery

  • and it glows red and you can see it burning in the air.

  • Not very vigorously but enough to stay red.

  • And then they dropped it into Neil's favourite cauldron

  • in which he often puts liquid oxygen.

  • When they dropped it in, and they did it several times,

  • there were the most amazing colours.

  • Essentially in all of it the iron burns.

  • It didn't all burn because at the end there were

  • bits of iron left in the bottom.

  • The chemistry is very simple:

  • The iron is reacting with oxygen.

  • There are three oxides of iron: FeO, Fe₂O₃, and Fe₃O₄.

  • Heaven knows which one was formed in these reactions, and it was probably a ghastly mixture of them

  • but the formation of all of these is highly exothermic:

  • It gives out a lot of heat.

  • So you have iron going into the liquid oxygen

  • producing a lot of heat, and, because it's so hot, it produces a lot of light.

  • In essence, what was happening is that you have small pieces of very hot iron

  • in liquid oxygen

  • and there were really beautiful colours.

  • A reaction like this is not very reproducible

  • because it depends exactly where you drop it, how the light is reflected,

  • where Brady was standing when he took the shot

  • so every picture is different, and nearly all of them are really beautiful.

  • Liquid oxygen is at a low temperature, -186 degrees centigrade

  • and you're dropping in a piece of hot metal

  • and you would expect that metal to cool down

  • but it was getting hotter.

  • The obvious interpretation, if you see these pictures,

  • is that somehow the iron is burning in this really cold liquid

  • but that's a contradiction. How can something be very hot

  • and very cold at the same time?

  • Now, what I thought was that the iron was so hot that

  • it was effectively in a bubble of oxygen gas

  • which comes bubbling up all the time

  • but was able to sustain the combustion.

  • But you can't really see that from the top

  • because you're looking through liquid oxygen.

  • So we decided we needed to do another experiment

  • looking at this vessel sideways

  • so you could see the liquid and at the same time you could see the iron at the bottom

  • and see what was happening.

  • But, experimentally, this is not easy.

  • The first problem is that liquid oxygen is very cold

  • so the air contains water vapour

  • which can condense and ice the whole thing up very quickly.

  • You could get round this by using a transparent Dewar flask,

  • A Thermos flask,

  • but they're quite expensive and the last thing you want to do

  • is to put hot metal inside it and crack your favourite Thermos vessel

  • and because these are evacuated, if they do crack,

  • they will explode spectacularly

  • which might make a good video,

  • but is unfortunate if it's an expensive piece of kit.

  • So, after discussion with Neil, we decided that the best thing to do

  • was to use an ordinary beaker

  • and to put it in a plastic box,

  • the one he'd carefully made,

  • and try and fill the box with either oxygen or nitrogen

  • which would not condense.

  • The experiment was moderately successful.

  • What I was hoping to see was the iron going in, sitting on the bottom,

  • and burning, surrounded by bubbling gas.

  • Of course, what happened is that when it went in,

  • there was such a bright flash

  • that was pretty difficult to film,

  • though Brady used some quite good tricks to get round this

  • and we couldn't get rid of all the ice forming

  • but the other thing, which we hadn't thought about,

  • was that the reaction was so violent

  • that burning bits of iron were pushed out of the beaker pretty quickly

  • and they landed on Neil's favourite plastic box

  • and set fire to it.

  • It wasn't actually the plastic

  • but it was the silicone sealant which caught fire.

  • I didn't think that silicone burnt very much at all

  • but when you see what happened to Neil's box,

  • we had demonstrated beyond doubt that when you have an atmosphere of oxygen,

  • silicone burns pretty well.

  • And I'm sad to say that Neil's box may be ruined.

  • It's certainly not in a good state.

  • But what was particularly surprising to me

  • was that the iron had got so hot

  • that it had actually gone through the glass of the beaker

  • and effectively punched a hole through it.

  • When we looked at the cauldron,

  • we also found lumps of iron in the bottom

  • because the molten iron was hot and started forming larger lumps

  • and these larger lumps have a smaller surface area,

  • so they don't burn so fast

  • and eventually they cool down and the reaction stops.

  • And you could tell that they were lumps of iron

  • because you could pick them up with a magnet.

  • So, what's the message?

  • Well, it's obvious, our experiment failed!

  • We did see something,

  • but we're still arguing what exactly we saw

  • and I don't think we can produce a really neat explanation of what happened

  • so we've got to go back to the drawing board

  • and design a better experiment.

  • The film we have taken has had such nice footage, particularly in the cauldron,

  • that we really wanted to show it to you

  • and I think it's really important to stress that when you're doing science,

  • not every experiment works

  • and you can still enjoy experiments that fail

  • and, so, enjoy our failure.

  • Very nice object.

  • Now, Steve I have the impression you think you know what this is.

  • This has got be a Davy lamp.

  • If you´re a superhero that would be your suit

  • And I hate to think what my origin story would be, but...

  • There is a second picture here.

Sometimes Brady and Neil do experiments that are just for fun

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鐵在液態氧中的燃燒 - 視頻的週期表 (Burning Iron in Liquid Oxygen - Periodic Table of Videos)

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    林宜悉 發佈於 2021 年 01 月 14 日
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