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  • Наконец выбрал название элемента 115,

  • и новое название Московиум.

  • Dear friends: they've finally chosen the name for Element 115, and the name is Moscovium.

  • Or perhaps, with a Russian accent, "ma-sko-vyum."

  • The reason they have chosen a Russian name

  • is because the element was synthesized for the first time in Dubna, somewhere to the north of Moscow.

  • Dubna is the big research center where element synthesis has been studied for the last 30 or more years.

  • Originally, under the leadership of Flyorov, after whom Flerovium was named quite recently.

  • As with the other elements, the way that you make these elements is by accelerating a very light ion

  • at very high speed into a heavy element and the nuclei fuse together.

  • Now the problem is that both nuclei are positively charged, so you need a lot of energy to overcome the repulsion, positive against positive.

  • But then, once it's made you don't want too much energy or it will immediately fall to bits.

  • It's a bit like trying to jump from the ground onto the top of a flag pole:

  • you might get there, but then over-balance straightaway and fall off again.

  • To do this, it's not just enough to choose the right atomic numbers,

  • but you have to choose the right isotope -- that's the atoms with the correct number of protons and neutrons --

  • so that in combination you get a stable number.

  • It's really important to understand that calcium-48 is a very rare isotope of calcium, less than 0.1% of naturally occurring calcium,

  • and it's very expensive to produce, and there is only one plant in the whole of Russia -- one plant in the whole world -- that can make calcium-48.

  • They ionise the calcium atoms, and then separate them magnetically as in a mass spectrometer,

  • So you need huge amounts of electricity to produce a few milligrams of the compound,

  • and apparently in one experiment in Dubna they used a million dollars' worth of calcium-48.

  • In these experiments you're bombarding the target Americium with trillions of calcium ions,

  • and only very rarely does the correct fusion take place, and you make one of the nuclei of Element 115.

  • Very fortunately, when you are successful the element comes out of the back almost in a straight line,

  • whereas when it blows up, fragments and something else, the fragments go in all directions.

  • So if you put a very narrow slit behind your target, you can get not just Element 115,

  • but the subset of fragments that contains that, and most of the junk goes away.

  • Moscovium is in Group 15, that's the group that begins with nitrogen, and then phosphorus.

  • And what is interesting about this group is that it includes arsenic, which is very poisonous.

  • Used to be used by poisoners to kill their wives or husbands.

  • But now as you go down the group, you come to bismuth, the element immediately above Moscovium.

  • Bismuth is surprisingly unpoisonous. It's even used in medicines.

  • So, it's a very interesting question: if you had a large quantity of Moscovium, would it be poisonous or would it not?

  • It's also interesting to think whether the chemistry would be similar to that of phosphorous, arsenic, and bismuth,

  • or whether, like bismuth, it would be almost like a metal.

  • You can get, for example, phosphorus pentafluoride, PF5, arsenic pentafluoride...

  • but you don't get these pentafluorides of bismuth, or at least you don't get them so easily.

  • So there'd be a lot of interesting chemistry, but unfortunately the technology so far will not allow you to do that sort of chemistry.

  • Moscow is one of my favourite cities, and so obviously I'm delighted.

  • Moscovium one of the few elements named after a capital city, and most of the others are not easily recognisable

  • because, for example Lutetium is named after Paris, but it's a Latin name that, unless you know, doesn't seem to relate to Paris at all.

  • So, I think it's a very good name.

  • As I mentioned before, Scottish viewers will like it because it has a symbol "Mc," and many Scottish surnames begin with Mc,

  • so there are going to be a lot of people in Scotland who can now spell their name with the elements of the Periodic Table.

  • Making Moscovium has been a fantastic piece of international collaboration because although the experiments were done in Russia,

  • they relied on having samples of Americium, which were made in America.

  • These are very specialist experiments where you need a particular facility that can make the isotope that you want.

  • We're talking about the starting material of milligrams or less,

  • so even if the process was very efficient, you would only get milligrams of the element,

  • and because of the low probability of forming them, we're talking about really quite small numbers of atoms being formed.

  • And in this paper, which is about the sensitive... the heavy elements,

  • they're giving the numbers of the atoms of these different elements: 118, 117, and so on.

  • So for 115, the highest number that any lab has seen, that's in Dubna, is 27 atoms of a particular isotope.

  • Just to make that clear, in my teacup there are probably 10 to the 26 or 10 to the 27 atoms.

  • It is really almost incalculable that you can start costing up this element atom by atom,

  • and each atom probably, if you take in all the costs, will cost millions of dollars, whereas with gold for millions of dollars you can get several kilos.

  • But for here, you got one atom, and it doesn't last very long, so it's the ultimate gift to give to somebody.

  • You might just have enough time to say "I love you" before the atom decays.

  • Brady: It's the million dollar atom. Prof. Poliakoff: Yes.

  • Brady: We already have an element named after Dubna, "Dubnium." Is it overkill, you know now having Moscovium,

  • are they, are they hogging all the names?

  • Prof. Poliakoff: I think it's fair enough: you have to bear in mind that there are some places that have at least four elements named after them,

  • particularly Ytterby, the small island near Stockholm, and there's Californium, Berkelium, Lawrencium,

  • and Livermorium are all in California, so I don't think it's unreasonable.

  • In my pocket I've got this,

  • and this is a real Nobel Prize medal.

  • It's a real Nobel Prize medal made of gold.

  • It's the medal that was won by my colleague at the Royal Society,

  • Sir Paul Nurse, the President, and I've borrowed it for this lecture.

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麝香 - 視頻的週期表 (Moscovium - Periodic Table of Videos)

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    林宜悉 發佈於 2021 年 01 月 14 日
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